Scopus Research — Mubeen Isam Mohammed Al-Sarhan

The authors would like to make the following corrections about the published paper [1]. The changes are as follows: The authors would like to replace the original version of Figure 2 The XRD pattern for synthesized UIO-66, MnFe2O4, and UIO-66–MnFe2O4 samples. with the following figure: The XRD pattern for synthesized UIO-66, MnFe2O4, and UIO-66–MnFe2O4 samples. The authors state that the scientific conclusions are unaffected. This correction was approved by the Academic Editor. The original publication has also been updated. © 2025 by the authors.

Activated carbon obtained from red algae Gracilaria changii was used as an adsorbent to remove Pb (II) and Cu (II) from an aqueous solution. The raw red algae were first impregnated with phosphoric acid, followed by thermal activation. The Box–Behnken design was used to optimize the activation process. The optimum activation parameters were 84%, 650 °C, and 175 min for acid concentration, activation temperature, and activation time, respectively. The obtained activated carbon had a high surface area of 867 m2/g. The removal of Pb (II) and Cu (II) was evaluated using a batch adsorption study. The effect of solution pH on the removal of metal ions was investigated within the range of 2–7. The effect of three important adsorption parameters (initial metal ion concentration, adsorbent dosage, and contact time) was analyzed using central composite design. The optimum removal of Pb (II) and Cu (II) was 76% and 36%, respectively. The adsorption kinetics obeyed the pseudo-second-order model, while the adsorption isotherm obeyed the Langmuir model. © The Author(s) 2023.

UV and solar-based photocatalytic degradation of 2,4-dichlorophenol (2,4-DCP) as an organic contaminant in ceramics industry wastewater by ZnS and Fe-doped ZnS NPs was the focus of this research. Nanoparticles were prepared using a chemical precipitation process. The cubic, closed-packed structure of undoped ZnS and Fe-doped ZnS NPs was formed in spherical clusters, according to XRD and SEM investigations. According to optical studies, the optical band gaps of pure ZnS and Fe-doped ZnS nanoparticles are 3.35 and 2.51 eV, respectively, and Fe doping increased the number of carriers with high mobility, improved carrier separation and injection efficiency, and increased photocatalytic activity under UV or visible light. Doping of Fe increased the separation of photogenerated electrons and holes and facilitated charge transfer, according to electrochemical impedance spectroscopy investigations. Photocatalytic degradation studies revealed that in the present pure ZnS and Fe-doped ZnS nanoparticles, 100% treatment of 120 mL of 15 mg/L phenolic compound was obtained after 55- and 45-min UV-irradiation, respectively, and complete treatment was attained after 45 and 35-min solar light irradiation, respectively. Because of the synergistic effects of effective surface area, more effective photo-generated electron and hole separation efficiency, and enhanced electron transfer, Fe-doped ZnS demonstrated high photocatalytic degradation performance. The study of Fe-doped ZnS's practical photocatalytic treatment capability for removing 120 mL of 10 mg/L 2,4-DCP solution made from genuine ceramic industrial wastewater revealed Fe-doped ZnS's excellent photocatalytic destruction of 2,4-DCP from real industrial wastewater. © 2023

In this article, we investigate the generalized (2+1)-dimensional shallow water wave equation which enables an unidirectional propagation of shallow-water waves. By noticing that the system is integrable, we could get the diverse forms of the solitary wave solutions by using the rogue wave and semi-inverse variational principle (SIVP) schemes. In particular, we investigate four solutions including rogue wave, soliton, bright soliton, dark soliton, and lump solutions. To achieve this, an illustrative example of the Helmholtz equation is provided to demonstrate the feasibility and reliability of the used procedure in this study. The effect the free parameters on the behavior of acquired figures to a few obtained solutions containing two nonlinear rational exact cases was also analyzed due to the nature of nonlinearities. The dynamic properties the obtained results are shown and analyzed by some density, two and three-dimensional images and also are presented the physical nature of obtained solutions. © 2023 The Author(s)

By using microorganisms and the microalgae Chlorella vulgaris in conjunction with sequencing batch reactors (SBRs), the performance of a wastewater treatment facility was studied. For this purpose, the effect of pH, temperature, COD inlet , and air flowrate on COD removal rate and residual was investigated. A single-factorial optimization method is utilized to optimize the amount of COD removal, and the best result is obtained with a pH of 8, CODinlet=600mg/l , and an airflow rate of 55 l/min. Under optimal conditions, the amount of residual COD in the effluent reached 36 mg / l , showing an augmentation in the efficiency of the desired system. Moreover, empirical correlations are proposed for double-factorial optimization of residual COD and COD removal. Also, a multilayer perceptron artificial neural network is proposed to model the process and predict the residual COD concentration. The useful technique of hyperparameter tuning is utilized to obtain the best result for the predictions. All the effective parameters, including the number of hidden layers, neurons, epochs, and batch size, are adjusted. Data from the experiments agreed well with the artificial neural network modeling results. For this modeling, the values of the correlation coefficient (R2) and mean absolute error (MAE) were obtained as 0.98 and 2%, respectively. © 2023, The Author(s).

Hitherto, a considerable amount of research has been carried out to investigate the equilibrium condition of adsorption process; nevertheless, there is no comprehensive study to evaluate the surface adsorption properties of MOFs. Therefore, the adsorption mechanism and equilibrium capacity of MOFs have not been fully understood. Furthermore, the mass transfer mechanism is still unknown and so it is not possible to predict the adsorption process using MOFs. In this work, a new metal–organic framework (MOF) named UIO-66–MnFe2O4 was synthesized as an adsorbent for oily wastewater treatment. In this way the effects of temperature, amount of adsorbent, adsorption time, pH, and pollutant initial concentration were studied in the treatment of oily wastewater using the UIO-66-MnFe2O4 MOF through the adsorption process. Furthermore, to examine the process of surface adsorption, different adsorption kinetic models (pseudo-first-order, pseudo-second-order, and Elovich) have been performed for the removal of oily pollutants on MOF adsorbents and the surface adsorption mechanism has been discussed carefully. Moreover, to investigate the mass transfer mechanism of oily pollutants in the surface adsorption process, different mass transfer models (Weber and Morris, liquid film diffusion, and Bangham and Burt) have been investigated on porous adsorbents, and finally the mass transfer mechanism of the adsorption process has been proposed. © 2023 by the authors.

This study assessed the quality of water in the Shatt Al-Hillah River by adopting some variables of physical, chemical, and heavy metal elements. The samples have been taken at six sites along the river in 2020 (from January to December). The water quality index has been determined by using the weighted-arithmetic method which is including a series of equations. Also, the model of Inverse-Distance-Weighting in the Geographic information system was applied to create a map of the water quality in the study area. Eleven physicochemical variables and five elements of heavy metals were comprised of calcium, magnesium, dissolved oxygen, Hydrogen Ions, chloride, sulfate, total hardness, total dissolved solids, turbidity, alkalinity, electric conductivity, cadmium, copper, iron, lead, and zinc. The results showed the values of the water quality index ranged from 245 to 253 (with a category of 200–300). The water quality index was rated as very poor for the selected locations along the Shatt Al-Hillah River. The GIS result illustrated the distributing map of water quality for the Shatt Al-Hillah River for household uses. The combination of the water quality index calculations with GIS in the current study might be used as a guide for future studies. © 2023, The Author(s).

Methane (CH4) is a greenhouse gas resulting from human activities, especially landfills, and it has many potential environmental issues, such as its major role in global warming. On the other hand, methane can be converted to liquid fuel or electricity using chemical conversion or gas turbine generators. Therefore, reusing such gases could be of great environmental and economic benefit. In this context, this study aims to estimate the emissions of methane gas from the landfills in Al-Hillah City, Iraq, from 2023 to 2070 and the producible electric energy from this amount. The estimating process was carried out using the Land GEM model and compared with traditional models. The obtained results demonstrated that the total estimated landfill methane emissions for 48 years are 875,217 tons, and the average annual methane emission is 18,234 tons based on a yearly waste accumulation rate of 1,046,413 tons and a total waste amount of 50,227,808 tons. The anticipated loads of methane gas can be utilized to generate about 287,442 MW/year of electricity from 2023 to 2070. In conclusion, the results obtained from this study could be evidence of the potential environmental and economic benefits of harvesting and reusing methane gas from landfills. © 2023, Springer Nature Limited.

It is important to determine the limits of flow regimes in the design of stepped weirs because of the hydraulic performance of each regime. The present study investigates the effect of downstream slope and rock fill materials on flow regimes in gabion stepped weirs. Nine physical models of gabion weirs were used in the experiments. The models’ downstream slopes ranged from 1:05 to 1:4 V:H. In addition, two types of rockfill materials: crushed stone of 0.42 porosity and rounded gravel of 0.38 porosity were used to study the effect of rockfill materials on flow regimes. The nominal size of the crushed stone was (37.5 mm-13.2 mm) D50 = 23 mm and the nominal size of the rounded gravel was (26.5 mm-13.2 mm) D50 = 16 mm. Each model has been tested with ten runs for discharge per unit width ranging (from 0.006 to 0.105 m3/sec. m) to cover all flow conditions and flow regimes. The onset of each flow regime for all physical models has been observed. The experimental data of the gabion stepped weirs have been used to develop equations to estimate the onset of each flow regime. The coefficient of correlation (R) of the developed equations ranged between 0.95 to 0.97. The results indicated on the steeper downstream slope models (1:0.5, 1:0.83), there is interference between the nappe and transition flow regimes. The nappe flow regime has not appeared on all steps at the same time. Moreover, the shape and size of the rockfill materials have an insignificant effect on flow regimes, especially at a high flow rate. © 2023, HARD Publishing Company. All rights reserved.

Surface water and groundwater are significant for population and other activities due to the decreasing surface water flow toward Iraq. Therefore, there is a need to analyze groundwater’s quality and classification and its applicability as an alternative in various human activities in the study area. This study utilized the groundwater quality index model for drinking uses (GW.Q.I.) and entered the resulting values in the GIS environment. This model was applied to 56 wells in Al-Hillah city by measuring twelve variables in each well. The measured variables were calcium (Ca), magnesium (Mg), sodium (Na), chloride (Cl), sulfate (SO4), bicarbonate (HCO3), total hardness (TH), total dissolved solids (TDS), nitrate (NO3), and electric conductivity (EC). The prediction map of GW.Q.I. was produced in the GIS. Then, the distributing map was divided into six categories based on the suitability of groundwater for drinking uses. The areas’ values of six categories with their ratings were about 5 km2 (excellent), 122 km2 (good), 610 km2 (poor), 63 km2 (very poor), 36 km2 (contaminated), and 24 km2 (very contaminated). For the entire study area, the average value of the GW.Q.I. was 177, classified as poor for drinking uses. © 2022, The Author(s).